Product ID:FRESH FORCE, 0480
MSDS Date:06/02/1993
FSC:6505
NIIN:00N035834
MSDS Number: BZRDQ

MANTEK DIV NCH CORP

IRVING, TX 75015
US

Emergency Phone: 214-438-1381

Info Phone: 214-438-1381

Preparer: R REEVES

Cage: HO204

NCH CORP / MANTEK DIV

152170 IRVING, TX 75015-2170 US

Telephone: 800-527-9919

Cage: 64796

NON-SPECIFIC, WERE JUDGED SECONDARY TO THE POOR HLTH

RTECS: 9999999ZZ

DIETHANOLAMINE GIVEN. SECONDARY & TERTIARY AMINES

RTECS: 9999999ZZ

SOME NITROSAMINES HAVE BEEN SHOWN TO BE CARCIN IN

RTECS: 9999999ZZ

CONT MAY CAUSE SENSIT & ALLERGIC SKIN RXN IN SML

RTECS: 9999999ZZ

EYES, SKIN, RESP SYS,

RTECS: 9999999ZZ

IF VOMITING OCCURS, GIVE FLUIDS AGAIN. GET

RTECS: 9999999ZZ

IF THESE RECOMMENDED LIM ARE/MAY BE EXCEEDED WHEN GEN

RTECS: 9999999ZZ

CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-, (R)-;

CAS: 5989-27-5

RTECS: GW6360000

OSHA PEL N/K

ACGIH TLV: N/K

FATTY ACID

OSHA PEL N/K

ACGIH TLV: N/K

ETHANOL, 2,2',2''-NITRILOTRI-; (TRIETHANOLAMINE) LD50 (ORAL

CAS: 102-71-6

RTECS: KL9275000

OSHA PEL N/K

ACGIH TLV: N/K

ETHANOL, 2,2'-IMINODI-; (DIETHANOLAMINE) (SARA 313)

CAS: 111-42-2

RTECS: KL2975000

OSHA PEL 3 PPM

ACGIH TLV: 0.46 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

AMIDES, C*3-C*18 AND C*18-UNSATURATED, BIS(HYDROXYETHYL)

CAS: 68155-07-7

OSHA PEL N/K

ACGIH TLV: N/K

TALL OIL

CAS: 61790-12-3

OSHA PEL N/K

ACGIH TLV: N/K

2,4-PENTANEDIOL, 2-METHYL-; (HEXYLENE GLYCOL)

CAS: 107-41-5

RTECS: SA0810000

OSHA PEL C 25 PPM

ACGIH TLV: C 25 PPM

ANIMALS INCL ANEMIA (RATS) & EFTS ON KIDNEY (RATS

RTECS: 9999999ZZ

ALSO OBSERVED IN THESE ANIMALS GIVEN EXAGGERATED

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE IRRIT, REDNESS,
SWELL & TEARING. EXCESS CONT W/LIQ CAN LEAD TO BLURRED VISION, SEV
DISCOMFORT, PAIN, CORNEAL DMG & POSS PERM DMG. SKIN: MAY CAUSE
IRRIT, SWELL & POSS ALLERGIC RXN S/SENSIT. INHAL: MAY CAUSE IRRIT
OF RESP TRACT, THROAT & NOSE. INTENTIONAL, EXCESS BRTHG OF VAPS CAN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: LEAD TO DIZZ, NAUS & LOSS OF
CONSCIOUSNESS. INGEST: MAY CAUSE IRRIT OF MOUTH & THROAT, ABDOM
PAIN, NAUS, DIZZ & LOSS OF CONSCIOUSNESS. INGEST OF LGE AMTS CAN
LEAD TO GI DISORDERS, VOMIT, DIA RR, DROW, FAINTNESS, WEAK,
COLLAPSE & COMA. SML AMTS OF ORANGE OIL ASPIR INTO LUNGS DURING
VOMIT/INGEST CAN (SUP DAT)
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING DERMATITIS
OR OTHER SKIN CONDITIONS.

First Aid:INHAL: REMOVE TO FRESH AIR. SEEK MED ATTN IF RESP IRRIT
DEVELOPS/IF BRTHG BECOMES DFCLT. EYE: RINSE W/WATER. REMOVE ANY
CONT LENSES & CONTINUE FLUSHING W/PLENTY OF WATER FOR AT LEAST 15
MIN. SEEK MED ATTN IF IRRIT DEVELOPS. SKIN: WASH AFFECTED AREAS
W/PLENTY OF SOAP & WATER FOR SEVERAL MIN. SEEK MED ATTN IF IRRIT
DEVELOPS. INGEST: GIVE 3-4 GLASSES OF WATER, BUT DO NOT INDUCE
VOMIT. (ING 15)

Flash Point Method:TOC
Flash Point:119F,48C
Lower Limits:0.7%
Upper Limits:6.1%
Extinguishing Media:USE FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DO NOT USE WATER. TREAT AS AN OIL FIRE WITH
CLASS B PROCEDURES.
Unusual Fire/Explosion Hazard:BURNING MAY PRODUCE OXIDES OF CARBON,
SULFUR, AND NITROGEN.

Spill Release Procedures:CONTAIN SPILL. PICK UP AND REUSE IF POSSIBLE.
PLACE INTO LABELED CONTAINERS FOR PROPER DISPOSAL. CAUTION: SPILL
CAN MAKE FLOOR SLIPPERY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT AND FLAME. KEEP
CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. ALL HANDLING EQUIPMENT
AND DRUM SHOULD BE PROPERLY GROUNDED.
Other Precautions:CAUTION: PRODUCT IS COMBUSTIBLE. FOLLOW LABEL
DIRECTIONS. KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL BEFORE
USING PRODUCT. AVOID EYE CONTACT AND EXCESSIVE BREATHING OF VAPORS.
STORE INDOOR AT TE MPERATURES BETWEEN 85F AND 100F.

Respiratory Protection:NOT NORMALLY REQUIRED UNLESS VAPOR
CONCENTRATIONS ARE EXCESSIVE OR EXCEED THE RECOMMENDED EXPOSURE
LIMITS, IN WHICH CASE A NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC
SOLVENTS SHOULD BE USED.
Ventilation:GENERAL EXHAUST IS USUALLY ADEQUATE TO PREVENT AIRBORNE
CONCENTRATIONS FROM EXCEEDING RECOMMENDED EXPOS LIMITS. (ING 16)
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID: CAN BE EXPLO. EFTS OF OVEREXP: CAUSE CHEM PNEUMIT, LUNG
DMG & MAY EVEN BE FATAL. CHRONIC: THE FOLLOWING EFTS ARE POSS DUE
TO TRIETHANOLAMINE ING: RPTD SKIN OVEREXP MAY LEAD TO IRRIT/BU RNS.
OBSERVATIONS IN ANIMALS INCL LIVER& KIDNEY EFTS, RSLTS FROM RPTD
EXPOS TESTS ON DEITHANOLAMINE IN LAB (ING 8)

Boiling Pt:B.P. Text:378F,192C
Vapor Pres:5
Vapor Density:6
Spec Gravity:0.85 (H*2O=1)
pH:8.5
Evaporation Rate & Reference:0.01 (BUTYL ACETATE=1)
Solubility in Water:EMULSION
Appearance and Odor:TRANSPARENT, ORANGE WITH ORANGE ODOR
Percent Volatiles by Volume:80

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, ALDEHYDES, KETONES, ACRYLATES, HALIDES, STRONG
OXIDIZERS. IODINE PENTAFLUOROETHYLENE CONT (SUP DAT)
Stability Condition to Avoid:AVOID HEAT, SPARKS OR OPEN FLAMES.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN, SMOKE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/ALL LOCAL, STATE &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.